MSDS Of Manganese Sulphate Monohydrate Powder--Rech Chemical Co. Ltd

  Material Safety Data Sheet

Manganese Sulfate Monohydrate

Section1: PRODUCT AND COMPANY IDENTIFICATION
CAS No.: 10034-96-5 (Monohydrate)
Molecular Weight: 169.01
Chemical Formula: MnSO4. H2O
Manufacture: RECH CHEMICAL CO. LTD
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Section 2: COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient                       CAS No          Percent         Hazardous                                      
 -----------------------            ------            -------           ---------       
 Manganese(II) Sulfate (1:1)  7785-87-7      98 - 100%     Yes                                                                 

Section 3: HAZARDS INDENTIFICATION
Emergency Overview
WARNING! HARMFUL IF SWALLOWED OR INHALED. AFFECTS LUNGS, CENTRAL NERVOUS SYSTEM, BLOOD AND KIDNEYS. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT.
Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Orange (General Storage)
Potential Health Effects
Inhalation:
Inhalation can cause a flu-like illness (metal fume fever). This 24- to 48-hour illness is characterized by chills, fever, aching muscles, dryness in the mouth and throat and headache. May irritate the respiratory tract. May increase the incidence of upper respiratory infections (pneumonia). Absorption of inorganic manganese salts through the lungs is poor but may occur in chronic poisoning.
Ingestion:
May cause abdominal pain and nausea. Although they are poorly absorbed through the intestines, inorganic manganese salts may produce hypoglycemia and decreased calcium blood levels should absorption occur.
Skin Contact:
May cause irritation with redness and pain.
Eye Contact:
May cause irritation, redness and pain.
Chronic Exposure:
Chronic manganese poisoning can result from excessive inhalation and ingestion exposure and involves impairment of the central nervous system. Early symptoms include sluggishness, sleepiness, and weakness in the legs. Advanced cases have shown fixed facial expression, emotional disturbances, spastic gait, and falling. Illness closely resembles Parkinson's Disease. Kidney effects, blood changes and manganese psychosis also may occur as a result of chronic exposure. Chronic inhalation exposure can cause lung damage.
Aggravation of Pre-existing Conditions:
Persons with impaired respiratory function, psychiatric or neurological disturbances, and nutritional deficiencies may be more susceptible to the effect of this substance.

Section 4: FIRST AID MEASURES
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.

Section5: FIRE FIGHTING MEASURES
Fire:        Not considered to be a fire hazard.
Explosion:  Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

Section6: ACCIDENTAL RELEASE MEASURES
Ventilate area of leak or spill. Keep unnecessary and unprotected people away from area of spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities.

Section7: HANDLING AND STORAGE
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

Section8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal Respirators:
If the exposure limit is exceeded and engineering controls are not feasible, a half face piece particulate respirator  may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest.. A full-face piece particulate respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified 



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